No explanation was given to Molecule Man's appearance in the Raft... in fact there were many villains in the Breakout arc that shouldn't have been there (dead, retired, etc.). It's been long speculated that Bendis just went through the OHOTMU Deluxe Edition and picked out villains he thought looked cool, without actually knowing anything about their statuses. Onbce he'd done that, he was free to use Molecule Man again later in DA.
I too would love to see Molecule Man and Volcana back, and not have either of them interested in being villains or heroes... just living their lives... but sometimes being sucked into the greater goings on in the MU.



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