The episodes will be up on thursdays for everyone.
ROH's website has now introduced a membership scheme. It actually looks pretty solid. For a membership fee($8 per month, $20 per quarter, or $60 per year) you get a whole bunch of goodies:
-An on demand video library with matches, full shows, and best ofs
-Access to the TV show on mondays instead of thursdays, with no ads and the ability to go back and watch any old episode
-15% off all merch at the store, inclusing items that are already on sale
-discounts on the ppvs
-access to exclusive online interviews/webchats with the wrestlers
-no ads on any video content on the site
-early access to tickets and new DVDs
On top of that, if you buy a yearly membership now, you get a free new logo shirt.
I'm actually really considering going for it. The only thing holding me back is that I don't see a way to look at what's all in the video library before signing up. It could be awesome, but it could also be lacking.