Off the top of my head, I can recall instances of her or others mentioning her pulse and heartbeat. Superman performed CPR on her in "JLA: A League of One. I would assume that she has the anatomy of a human being.
In Hippolyta's first life, she was pregnant when she was murdered. The soul of the unborn child was reincarnated as Diana.
The Amazons were formed from the clay at the bottom of a sea...I can't remember which at the moment. They took their first breath when they reached the surface.
She's been shot before. A speedster assassin named Mayfly shot her in the head, putting her in a coma. That's the only non-magic based one I can think of at the moment.
When the Amazons were created from the clay of the sea bed, Hippolyta was the first to break the water's surface, which marked her destiny as queen of the Amazons.



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