Issue numbers if it helps, though Purplevit, had one of those already.
Xmen (Vol 2) #52
Mark Waid story titled "Collector's Item". Gambit/Dark Beast/Bishop story with Sinister. Showing Sinister's concern for Gambit's health.
Apocalypse and "unique heritage", Xmen (vol 2) #184
Weapon X: First Class #3 Sinister hiring teen Gambit to get a diary, that Gambit later destroys.
Xmen Prime: Gambit's coma
XMen (Vol 2) 45 - where Sinister shows up to talk to Gambit
Those should get you all the stuff you are looking for, there is only one issue I can't find at the moment and well, I'm done looking for now. Anyway - there you go - evidence. Uncannyxmen.net is great for this sort of thing btw.

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